In an n-type silicon, which of the following statement is true: (a) Electrons are majority carriers and trivalent atoms are the dopants. (b) Electrons are minority carriers and pentavalent atoms are the dopants. (c) Holes are minority carriers and pentavalent atoms are the dopants. (d) Holes are majority carriers and trivalent atoms are the dopants.
Hint. Decide first which dopant produces n-type material, then identify which carrier is in the minority.
An n-type semiconductor is made by doping silicon with a pentavalent element such as phosphorus, arsenic or antimony. Silicon has four valence electrons, so a pentavalent atom contributes one electron more than the four bonds require, and that spare electron is loosely bound and easily freed.
The result is that electrons are the majority carriers and holes are the minority carriers, the holes arising only from thermal generation.
Checking each option:
- (a) Wrong dopant. Trivalent atoms produce p-type material, not n-type.
- (b) Electrons are the majority carriers in n-type, not the minority.
- (c) Correct on both counts: holes are indeed the minority carriers, and the dopant is indeed pentavalent.
- (d) This describes p-type material.
Option (c) is a slightly indirect way of describing n-type silicon, since it names the minority carrier rather than the majority one, but every part of the statement is true.
✦ (c) Holes are minority carriers and pentavalent atoms are the dopants
