Solutions — Class 10 Science (Samacheer Kalvi)
TN State Board (Samacheer Kalvi) Class 10 Science, Chemistry — Chapter 9. Mixtures, concentration, and how salts interact with water in the air.
1. About this chapter
This chapter covers solutions (solute + solvent), their concentration, solubility, hydrated/anhydrous salts, and the special behaviour of efflorescent, deliquescent and hygroscopic substances.
2. Solution, solute and solvent
- A solution is a homogeneous mixture of two or more substances.
- Solute = substance dissolved (smaller amount); solvent = substance that dissolves it (larger amount). Water is the universal solvent.
- Types by amount of solute: dilute, concentrated, saturated (no more solute dissolves at that temperature), unsaturated, and supersaturated.
3. Concentration of a solution
- Mass percentage = (mass of solute / mass of solution) × 100.
- Volume percentage = (volume of solute / volume of solution) × 100.
- Solubility: the maximum amount of solute that dissolves in 100 g of solvent at a given temperature.
4. Hydrated salts and water of crystallisation
- Water of crystallisation: the fixed number of water molecules chemically combined in a crystal. e.g. CuSO₄·5H₂O (blue), Na₂CO₃·10H₂O (washing soda).
- Hydrated salt: contains water of crystallisation; anhydrous salt: has none (e.g., white anhydrous CuSO₄).
5. Efflorescence, deliquescence, hygroscopy
| Term | Behaviour | Examples |
|---|---|---|
| Efflorescent | hydrated salt loses water of crystallisation to air, turning powdery | Na₂CO₃·10H₂O |
| Deliquescent | absorbs so much moisture it dissolves into a solution | NaOH, CaCl₂, MgCl₂ |
| Hygroscopic | absorbs moisture but does not dissolve | conc. H₂SO₄, silica gel, quicklime (CaO) |
6. Worked examples
Example 1. 20 g of salt is dissolved in 80 g of water. Find the mass percentage of the solution. Mass of solution = 20 + 80 = 100 g; mass % = (20/100)×100 = 20%.
Example 2. Why does washing soda become powdery when left in air? It is efflorescent — it loses its water of crystallisation to the air.
Example 3. Why is anhydrous calcium chloride used as a drying agent? It is deliquescent / hygroscopic — it absorbs moisture from the surroundings.
7. Common mistakes
- Mistake: Confusing deliquescence with efflorescence. Fix: Efflorescent salts lose water; deliquescent substances absorb water and dissolve.
- Mistake: Calling every mixture a solution. Fix: A solution must be homogeneous.
- Mistake: Mixing up hygroscopic and deliquescent. Fix: Hygroscopic absorbs moisture but does not dissolve; deliquescent dissolves.
8. Practice (book-back style)
- Define a solution; name the solute and solvent in sugar syrup.
- What is water of crystallisation? Give an example.
- Differentiate efflorescent and deliquescent substances.
- 25 g of solute in 100 g of solution — find the mass percentage.
- Why is silica gel placed in packaging?
9. Answer key
- A homogeneous mixture; in sugar syrup sugar is the solute, water the solvent.
- The fixed water molecules combined in a crystal; e.g., CuSO₄·5H₂O.
- Efflorescent loses water of crystallisation to air; deliquescent absorbs moisture and dissolves.
- Mass % = (25/100)×100 = 25%.
- It is hygroscopic and keeps the contents dry by absorbing moisture.
10. Quick revision
- Chemistry Ch 9 · solutions, concentration, hydrated salts.
- Solution = homogeneous mixture (solute + solvent).
- Mass % = (solute/solution)×100; saturated = max solute at that temperature.
- Water of crystallisation: CuSO₄·5H₂O, Na₂CO₃·10H₂O.
- Efflorescent loses water; deliquescent absorbs & dissolves; hygroscopic absorbs but does not dissolve.
